Experimental and mechanistic study on the water resistance of sodium methylsilicate-modified raw soil
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摘要: 以内蒙古中部生土为基材,采用表面涂刷与内掺改性两种方法,探究甲基硅酸钠(SM)对生土材料耐水性能的强化机制。通过60 min静水浸泡和120 min动态冲刷试验得出:(1)强度性能:表面涂刷与内掺试件平均抗压强度较对照组分别提升16.67%和47.66%,(2)静水性能:表面涂刷与内掺试件平均吸水率为1.57%和2.17%,软化系数达0.80和0.81;(3)抗冲刷能力:表面涂刷与内掺试件平均吸水率为0.97%和2.11%,软化系数为0.55和0.63;(4)微观机制:表面涂刷改性形成外部包裹式防水层,而内掺改性通过SM与土颗粒生成聚硅氧烷膜,同步增强防水性与结构稳定性。Abstract: This study investigates the reinforcement mechanism of sodium methylsilicate (SM) on the water resistance of raw soil materials using surface coating and internal incorporation modification methods, with raw soil from central Nei Mongol as the base material. Through 60-minute static water immersion and 120-minute dynamic scouring tests, the following results were obtained: (1) Mechanical properties: Surface-coated and internally incorporated specimens demonstrated 16.67% and 47.66% higher average compressive strength, respectively, compared to the control group. (2) Hydrostatic performance: The average water absorption rates were 1.57% and 2.17% for surface-coated and internally incorporated specimens, with corresponding softening coefficients reaching 0.80 and 0.81. (3) Scouring resistance: The average water absorption rates measured 0.97% and 2.11%, with softening coefficients of 0.55 and 0.63, respectively. (4) Microscopic mechanism: Surface coating modification forms an external encapsulated waterproof layer, while internal incorporation modification generates polysiloxane films through SM-soil particle interactions, simultaneously enhancing both waterproofing capability and structural stability.
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Key words:
- modified raw soil /
- compressive strength /
- water resistance /
- sodium methylsilicate
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表 1 土壤粒径分析(质量分数)
Table 1. Soil particle size analysis (mass fraction)
筛孔尺寸/mm >2 2~1 1~0.5 0.5~0.25 0.25~0.1 0.1~0.075 <0.075 占比/% 0.82 2.40 5.00 10.76 42.89 24.66 13.47 表 2 面掺甲基硅酸钠(浓度)试验配合比
Table 2. Experimental mix ratio of sodium methylsilicate (concentration) for surface doping
编号 JMC-10 JMC-15 JMC-20 JMC-25 JMC-30 SM浓度/% 1 1.5 2 2.5 3 编号 JMC-35 JMC-40 JMC-45 JMC-50 JMC-55 SM浓度/% 3.5 4 4.5 5 5.5 表 3 内掺甲基硅酸钠(质量)试验配合比
Table 3. Experimental mix ratio for the internal doping of sodium methylsilicate (by mass)
编号 JNC-03 JNC-05 JNC-07 JNC-09 JNC-11 SM掺量/% 0.3 0.5 0.7 0.9 1.1 编号 JNC-13 JNC-15 JNC-17 JNC-19 JNC-21 SM掺量/% 1.3 1.5 1.7 1.9 2.1 表 4 面层涂刷SM改性生土试块浸泡试验耐水性情况
Table 4. Water resistance of surface layer coated with SM modified raw soil test block soaking test
浸水时间/min 试块浸水效果 10 
20 
30 
40 
50 
60 
90 
120 
表 5 内掺甲基硅酸钠改性生土试块浸泡试验耐水性情况
Table 5. Water resistance of soil-modified raw soil test block doped with sodium methylsilicate
浸水时间/min 试块浸水效果 10 
20 
30 
40 
50 
60 
90 
120 
表 6 面涂SM试块冲刷前后强度变化及软化系数
Table 6. Strength change and softening coefficient of SM coated test block before and after scouring
方法 性能指标 JMC-30 JMC-40 JMC-50 面层涂刷
甲基硅酸钠浓度/% 3 4 5 (冲刷前/后抗压强度)/MPa 4.36/− 4.48/2.28 4.54/2.63 软化系数 0.51 0.58 质量变化率/% −23.19 0.37 1.57 表 7 SM不同改性生土样本的微观形貌
Table 7. Micromorphologies of different modified raw soil samples with SM
电镜倍数 ST(未掺入甲基硅酸钠) JNC(内掺1.1%甲基硅酸钠) JMC(面涂5%甲基硅酸钠) 500 


2000 


5000 


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