Strength mechanical properties and microscopic mechanism of unburned artificial aggregate based on solid wastes
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摘要: 随着建筑行业对天然骨料需求的增长,资源短缺与环境问题日益凸显,开发人工骨料意义重大。本文以粉细砂、黏土、水泥等为原料制备固废基人工骨料,研究其力学性能,并探究其微观机制。通过无侧限抗压强度试验,发现制样压力在5~10 MPa时,试样强度明显上升,10~15 MPa时轻微上升,15 MPa以上强度不再随压力增加而持续增加。此外,50%剂泥比下免烧人工骨料强度有显著提升,同时在粉细砂中辅掺黏土可改良土体性质,添加40%黏土时人工骨料强度提升最显著,但过量掺入会使强度下降。利用扫描电镜(SEM)和压汞技术(MIP)对材料微观结构进行表征,结果表明,50%剂泥比试样水化产物最多且分布均匀,75%剂泥比试样内部形成片状结构,抑制水泥水化,导致试样强度降低;15 MPa制样压力下试样孔隙直径主要分布在5~20 nm。本研究确定了固废基免烧人工骨料的最佳制备参数,为解决天然骨料短缺问题、实现资源可持续利用提供了理论依据和技术支持。Abstract: As the demand for natural aggregates in the construction industry increases, resource shortages and environmental concerns have become more prominent, making the development of artificial aggregates highly significant. This study investigates solid waste-based artificial aggregates prepared from fine sand, clay, cement, and other raw materials, focusing on their mechanical properties and underlying microscopic mechanisms. The unconfined compressive strength tests revealed that when the sample preparation pressure ranged from 5~10 MPa, strength increased significantly, with a slight increase observed between 10~15 MPa. Above 15 MPa, no further increase in strength was observed. Furthermore, the strength of unburned artificial aggregates was notably improved at a 50% agent-to-mud ratio. The addition of clay to fine sand enhanced soil properties, with strength peaking when 40% clay was added; however, excessive clay content reduced strength. Microstructural analysis using scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) indicated that the sample with a 50% cement ratio exhibited the highest and most evenly distributed hydration products. In contrast, the 75% cement ratio sample formed a lamellar structure that hindered cement hydration, leading to reduced strength. Pore diameters were mainly in the 5~20 nm range under a 15 MPa preparation pressure. This study establishes the optimal parameters for producing solid waste-based artificial aggregates, offering a theoretical and technical foundation for addressing natural aggregate shortages and promoting sustainable resource utilization.
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表 1 试验用粉细砂物理性质指标
Table 1. Physical characteristic indicators of experimental soils
土类 密度/(g∙cm−3) 含水率/% 液限/% 塑限/% 粉粒占比/% 黏粒占比/% 粉细砂 1.64 26 34 25 98.4 1.6 黏土 1.68 42 45 27 45.9 54.1 表 2 多组试样配比表
Table 2. Proportion table of multi-group samples
制样压力
/MPa水泥
掺量/%固体
激发剂掺量/%液体
激发剂掺量/%密度
/(g∙cm−3)养护
时间/d3 22.2 11.1 0.1 1.94 3~28 5 22.2 11.1 0.1 1.94 3~28 10 22.2 11.1 0.1 1.99 3~28 15 25 0 0.1 2.05 3~28 15 23.5 5.9 0.1 2.05 3~28 15 22.2 11.1 0.1 2.05 3~28 15 21.1 15.8 0.1 2.05 3~28 20 22.2 11.1 0.1 2.08 3~28 -
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